Researchers at Case Western Reserve University are developing ways to convert waste into fuels and other products, using processes that are energy efficient and powered by renewable sources.

More specifically, they're close to resolving the challenge of converting carbon dioxide (CO₂), a major greenhouse gas, into valuable chemicals using electricity.

CO₂ can be a useful raw material for making commodity chemicals and fuels. But the process of creating the necessary reaction isn't easy because it requires high pressures, high temperatures and special materials.

"Our modern society is in critical need of technologies that can capture the CO₂ from waste—or even air—and convert it to products at benign conditions," said Burcu Gurkan, professor of chemical engineering at Case School of Engineering. "Electrochemical conversion of carbon dioxide is an unresolved problem that is more than 150 years old."

Until now, research has mainly focused on developing catalyst materials and understanding the energy-intensive CO₂ conversion reaction in water-based electrolytes. Yet challenges remain because water-based systems have limited capacity for CO₂. In addition, the process includes unwanted side reactions, such as hydrogen gas emissions.

But in a study published this fall in the European journal Angewandte Chemie, the Case Western Reserve research team demonstrated that the ionic liquids they developed effectively capture and convert CO₂ in an electrochemical process.

Ionic liquids are salts that melt below 100°C. The ones that Gurkan's group developed are liquid at room temperature. These ionic liquids also are unique in that they have high capacity for CO₂ capture and maintain electrochemical stability. As a result, the team achieved the desired electrochemical process.

"Our approach focuses on ionic liquid electrolytes that can alter the thermodynamics and product distribution due to kinetic effects which can be further tuned, thanks to the flexibility in ionic liquid design," Gurkan said.

The study, led by Oguz Kagan Coskun, a doctoral student in Gurkan's group, combined spectroscopic and electroanalytical techniques to reveal the fundamental mechanisms necessary for ionic liquids to activate the CO₂ reduction reaction at the copper electrode surface.

The group reported needing less energy to drive the reaction and noted that it could lead to creation of a variety of industrially relevant products—without the unwanted side products found in the traditional electrolysis process.

Further, the report explains crucial aspects influencing the properties of the reaction environment for the effective use of CO₂. This additional information contributes to a deeper understanding of reaction environment, especially concerning unconventional electrolytes.

The team plans to examine the individual reaction steps further to inform subsequent electrolyte designs. The ultimate goal: better control of the chemicals from the reaction and advance the electrochemical approaches to CO₂ recycling.